A comprehensive approach to vibrational analysis of polyatomic molecules and a method of calculating coriolis forces

Abstract

Mathematical formulation of molelcular vibrational problems is presented. The basic parametric representation procedure and the theory of the method of Redington and Aljibury for the force field determination are given. A brief account of mean amplitudes of vibration, Coriolis coupling constants and rotational distortion constants i s given along with explicit texpressions for these constants in terms of the normal coordinate transformation matrix L. A gist of the present work is also added.