Investigation of transition metal dichalcogenide based Layered superconductors

Abstract

The discovery of superconductivity in 1911 by Heike Kamerlingh Onnes is one of the most significant foundations of science that leads to a number of groundbreaking research in the field of condensed matter physics. Superconductors are highly fascinating due to their exotic properties like perfect conductivity and perfect diamagnetism, and their potential for wide range applications. Discovery of super- conductivity in new materials has always been subject of interest among the material scientists. Several materials are investigated to demonstrate superconductivity, of which the cuprates, iron oxipnictides and transition metal dichalcogenides are most studied systems for last few decades. Recently, a new class of MTCh 2 (M: Metal, T: Transition metal, Ch: Chalcogen element with M 6 = T) type intercalated transition metal dichalcogenide based layered superconductors like PbTaSe 2 , SnTaS 2 and PbTaS 2 has re-established the interest in these systems. These materials apart from being superconducting also possess nontrivial topological electronic band structure that makes them strong candidates to realize novel quantum states like topological superconductors and Majorana fermions. In this thesis we have presented the synthesis, characterization and physical properties of transition metal dichalcogenide based layered PbNbS 2 , PbNbSe 2 and SnTaS 2 systems. Polycrystalline samples of all these compounds were prepared via solid state reaction route following the sealed tube method. This thesis in- troduces two new superconductors PbNbS 2 and PbNbSe 2 , and also discuss theii superconducting properties of polycrystalline SnTaS 2 . All three systems crystallize in centrosymmetric hexagonal structure with space group P 6 3 /mmc, containing alternative M (= Pb or Sn) and TCh 2 (NbS 2 , NbSe 2 or TaS 2 ) layers in which T atom is accommodated in the trigonal-prismatic co-ordination with Ch atoms while M occupies the octahedral site. The PbNbS 2 system is found to be superconducting below T c and#8764; 8.8 K. Superconductivity in PbN