Design of Coatings Embedded with Tolerant Tailored and Responsive Underwater Oil Wettability and Oil Adhesion

Abstract

quotThe anti-oil wettability of various naturally existing underwater creatures has inspired researchers to develop artificial super oil repellent interfaces for multiple applications in engineering, healthcare, and environmental remediation. In the past, several approaches were adopted to artificially fabricate underwater oil-repellent surfaces, formally known as underwater superoleophobicity, by co-optimizing hydrophilic chemical composition and rough micro/nano-structures on their surface. However, the earlier reported approaches in deriving underwater superoleophobicity were unable to associate some other essential properties, such as, physical and chemical durability, adaptive tuning of oil adhesion, and transparency in the prepared surfaces. Here, a facile 1, 4-conjugate addition reaction is exploited to derive covalently crosslinked chemically reactive coatings on various surfaces loaded with residual chemical functionalities that provide the opportunity to embed underwater superoleophobicity through appropriate post-covalent modifications. While the covalent crosslinking tailored mechanical property, the adequate chemical post-modification customized oil adhesion and optical transparency. The thesis entitled Design of Coatings Embedded with Tolerant, Tailored and Responsive Underwater Oil Wettability and Oil Adhesion is presented in six chapters. Chapter 1 introduces bio-mimicked underwater superoleophobic surfaces, the existing challenges associated with conventional artificial fabrication approaches, and the objectives of the thesis work. Chapter 2 demonstrates the fabrication of a dually reactive multilayer coating following the 1, 4-conjugate addition reaction and the post-covalent modification of the multilayer coating to immobilize highly sensitive bare micro-meter sized nematic liquid crystal (LC) droplets underwater for single LC droplet based repetitive sensing application. Chapter 3 accounts for the utilization of the dually reactive multilayer coating to develop various responsive underwater sup