Molecule to supramolecule effect of assembly on the molecular properties of h bonded chiral assembly of coordination complexes with amino acid derivatives

Abstract

Metal complexes of amino acid derived reduced Schiff base ligands generated several interesting architectures including chiral capsule channels and cavity owing to their flexibility H bonding ability and inherent chirality 1 2 In this thesis we have explored the chemistry of L leucine derivative Figure 1 and characterized a set of spontaneously formed crown ether analogue multinuclear assemblies binding both cation and anion of a binary salt in the solid state Considerable amount of wor