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http://hdl.handle.net/10603/450679
Title: | Synthesis of Card and Nitrogen Hetero-Cycle Compounds |
Researcher: | Sahu, Archana Kumari |
Guide(s): | Saikia, Anil |
Keywords: | Chemistry Chemistry Applied Physical Sciences |
University: | Indian Institute of Technology Guwahati |
Completed Date: | 2022 |
Abstract: | The contents of this thesis have been divided into five chapters based on the results of experimental work performed during complete course of research period. Chapter 1 mainly discusses about tandem reactions, its types and tandem reactions carried out on alkynes and donor-acceptor cyclopropanes. Chapter 2 describes the synthesis of dibenzocyclohepta[1,2-a]naphthalene derivatives from alkynyl benzyl alcohols and phenylacetaldehydes via sequential electrophilic addition and double Friedel–Crafts reactions. Chapter 3 illustrates In(OTf)3-catalyzed one-pot tandem Mannich/Conia-ene cyclization reaction for the construction of tetrahydro-1H-pyrrolo[2,1-a]isoindolone-1,1-dicarboxylates from N-propargyl amido alcohols with 1,3-dicarbonyl compounds. Chapter 4 discloses a direct method for the synthesis of dibenzoyl tetrahydro-[1,5]diazocinodiisoindolediones from N-propargyl amido alcohols employing Bi(OTf)3 as catalyst. Chapter 5 demonstrates the synthesis of 3C-homologated active methylene substituted 2H-indazoles via a sequential Ni(II) catalysed ring opening of donor acceptor cyclopropanes with arylamines followed by Sn(II) mediated reductive cyclization reaction |
URI: | http://hdl.handle.net/10603/450679 |
Appears in Departments: | DEPARTMENT OF CHEMISTRY |
Files in This Item:
File | Description | Size | Format | |
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01_fulltext.pdf | Attached File | 16.49 MB | Adobe PDF | View/Open |
04_abstract.pdf | 146.04 kB | Adobe PDF | View/Open | |
80_recommendation.pdf | 548.59 kB | Adobe PDF | View/Open |
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