Microwave Rotation Tunnelling Spectroscopic and Theoretical Studies on Weakly Bound Molecular Complexes Intermolecular Bonding across the Periodic Table

Abstract

Intermolecular interactions appear to be well understood in a broad sense today; at a deeper molecular level, it is still evolving. Spectroscopy in this isolated state proved to be a first step toward understanding the intermolecular interaction at the molecular level. Microwave spectroscopy offers precise structural information on the near-equilibrium geometry of small dimers and trimers in isolation. Computational studies like the Atoms in Molecules (AIM), non-covalent index plots (NCI), and natural bond orbital analysis (NBO) are used to augment rotational spectroscopic investigations. The Ka = 1 transitions of H2S dimer and several isotopomers were observed in a pulsed nozzle Fourier transform microwave spectrometer. These transitions give unequivocal proof that, at ultra-low temperatures, hydrogen sulfide forms S-Hand#11827;and#11827;and#11827;S hydrogen-bonded dimer in the same way as water does, even though ice and solid H2S seem substantially different in bulk. Also, using the AIM theory, we have shown that H2S dimer satisfies the necessary and sufficient criterion proposed by Koch and Popelier to be hydrogen-bonded. Although we recently highlight the arbitrariness in relying on some computational tools to characterize a bond. The weakly bound trimer between two hydrogen sulfide molecules and one water molecule, (H2S)2H2O, was identified from its rotational spectrum. The break with axial molecular symmetry allowed us to investigate (H2S)2H2O at a level of structural detail that has not yet been possible for (H2O)3 and (H2S)3 with rotational spectroscopy owing to their zero-dipole moment. Analysis of experimental results reveals that the three monomers are bound in a triangular arrangement through S-Hand#11827;and#11827;and#11827;S, O-Hand#11827;and#11827;and#11827;S, and S-Hand#11827;and#11827;and#11827;O hydrogen bonds with a fair amount of co-operativity. High-resolution spectroscopic data may be used to validate the correctness of a model intermolecular potential energy hyper-surface. In this regard, we have measured the donor-acceptor interchange tunnelling splitting in the ground vibrational state of Ar...