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http://hdl.handle.net/10603/426606
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DC Field | Value | Language |
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dc.date.accessioned | 2022-12-17T10:38:10Z | - |
dc.date.available | 2022-12-17T10:38:10Z | - |
dc.identifier.uri | http://hdl.handle.net/10603/426606 | - |
dc.description.abstract | The research work delineates a flexible and novel route for the diastereoselective construction of diversely substituted N-heterocyclic variants as valuable scaffolds for natural products and pharmaceuticals, starting from an easily accessible prochiral and#945;-phenyl-and#946;-enamino ester. By taking advantage of the Cp2TiCl-mediated reductive epoxide opening-cyclization, an expedient and unified approach has been accomplished to gain access to a handful of iridoid monoterpenes in an enantiomerically divergent manner starting from (+)-and#946;-citronellene. Also, a radical approach to build oxa-quaternary centers, structural feature of various natural-products-inspired synthons have been undertaken via Cp2TiCl-mediated reductive epoxide opening-cyclization protocol. Furthermore, the feasibility of Cp2TiCl-promoted radical cyclization has also been explored onto N-tethered epoxy indoles which provide an efficient route for the construction of pyrrolo/piperidino[1,2-a]indole derivatives. newline | - |
dc.format.extent | v, 278 | - |
dc.language | English | - |
dc.rights | university | - |
dc.title | A Mitsunobu Michael Reaction Sequence to N Heterocyclic Variants and Ti III Mediated Synthesis of Terpenoids and N Fused Indoles | - |
dc.title.alternative | A Mitsunobu-Michael Reaction Sequence to N-Heterocyclic Variants and Ti(III)-Mediated Synthesis of Terpenoids and N-Fused Indoles | - |
dc.creator.researcher | Afzal, Khan Hina Parveen | - |
dc.subject.keyword | Chemistry | - |
dc.subject.keyword | Chemistry Organic | - |
dc.subject.keyword | Physical Sciences | - |
dc.contributor.guide | Chakraborty, Tushar Kanti | - |
dc.publisher.place | Bangalore | - |
dc.publisher.university | Indian Institute of Science Bangalore | - |
dc.publisher.institution | Organic Chemistry | - |
dc.date.completed | 2019 | - |
dc.date.awarded | 2020 | - |
dc.format.dimensions | 30 | - |
dc.format.accompanyingmaterial | None | - |
dc.source.university | University | - |
dc.type.degree | Ph.D. | - |
Appears in Departments: | Organic Chemistry |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
01_title.pdf | Attached File | 127.6 kB | Adobe PDF | View/Open |
02_prelim pages.pdf | 271.64 kB | Adobe PDF | View/Open | |
03_table of contents.pdf | 152.38 kB | Adobe PDF | View/Open | |
04_abstract.pdf | 484.6 kB | Adobe PDF | View/Open | |
05_chapter 1.pdf | 5.82 MB | Adobe PDF | View/Open | |
06_chapter 2.pdf | 3.47 MB | Adobe PDF | View/Open | |
07_chapter 3.pdf | 7.82 MB | Adobe PDF | View/Open | |
08_annexure.pdf | 320.88 kB | Adobe PDF | View/Open | |
80_recommendation.pdf | 6.53 MB | Adobe PDF | View/Open |
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