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http://hdl.handle.net/10603/423410
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DC Field | Value | Language |
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dc.coverage.spatial | ||
dc.date.accessioned | 2022-12-09T06:36:06Z | - |
dc.date.available | 2022-12-09T06:36:06Z | - |
dc.identifier.uri | http://hdl.handle.net/10603/423410 | - |
dc.description.abstract | Organometallic compounds are increasingly being used to mediate or catalyze reactions in the synthesis of pharmaceuticals and fine chemicals. In this context, Palladium- catalyzed cross-coupling reactions are extremely useful for the construction of organic molecules in both academia and industry. Palladium-catalyzed cross-coupling reactions are coupling reactions that take place between an electrophile and a nucleophile (usually an organometallic reagent) and are catalyzed by palladium precursors. Organo halides, such as organo iodides and bromides, have traditionally been used as electrophiles in cross-coupling reactions. Despite the fact that organo iodides and bromides were excellent synthons, their cost and availability limited their utility. Because of this, organo pseudo halides including oxo-sulfonates and aza-sulfonates have been successfully used in transition metal-catalyzed cross-coupling reactions to form various C-C bonds. Even so, these electrophiles can produce an unavoidable amount of waste. Disposal of this waste has been a major issue for industries in bulk scale synthesis. As a result, there is a pressing need to improve environmentally friendly cross-coupling reactions. Triazoles would be regarded as excellent synthons for organic synthesis in this case. In denitrogenative transformation, these will expel eco-friendly molecular nitrogen as a by-product. Triazoles can deliver a variety of nitrogen-containing organic compounds in an efficient and regioselective manner on cross- coupling reactions with various nucleophiles. In this regard, 1,2,3-Benzotriazin-4(3H)-one is a well-known triazole molecule that can be used in a variety of pharmaceuticals and agrochemicals newline | |
dc.format.extent | ||
dc.language | English | |
dc.relation | ||
dc.rights | university | |
dc.title | Nickel and Palladium Catalyzed Denitrogenative Reaction of 1 2 3 Benzotriazin 4 3h One for Synthesis of Ortho Functionalized Benzamides and Heterocyclic Compounds | |
dc.title.alternative | ||
dc.creator.researcher | Hari Balakrishnan, M | |
dc.subject.keyword | Chemistry | |
dc.subject.keyword | Chemistry Medicinal | |
dc.subject.keyword | Physical Sciences | |
dc.description.note | ||
dc.contributor.guide | Mannathan,S | |
dc.publisher.place | Kattankulathur | |
dc.publisher.university | SRM Institute of Science and Technology | |
dc.publisher.institution | Department of Chemistry | |
dc.date.registered | ||
dc.date.completed | 2022 | |
dc.date.awarded | 2022 | |
dc.format.dimensions | ||
dc.format.accompanyingmaterial | DVD | |
dc.source.university | University | |
dc.type.degree | Ph.D. | |
Appears in Departments: | Department of Chemistry |
Files in This Item:
File | Description | Size | Format | |
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01_title page.pdf | Attached File | 388.45 kB | Adobe PDF | View/Open |
02_preliminary page.pdf | 805.75 kB | Adobe PDF | View/Open | |
03_content.pdf | 422.33 kB | Adobe PDF | View/Open | |
04_abstract.pdf | 319.76 kB | Adobe PDF | View/Open | |
05_chapter 1.pdf | 2.01 MB | Adobe PDF | View/Open | |
06_chapter 2.pdf | 791.39 kB | Adobe PDF | View/Open | |
07_chapter 3.pdf | 1.13 MB | Adobe PDF | View/Open | |
08_chapter 4.pdf | 1.18 MB | Adobe PDF | View/Open | |
09_chapter 5.pdf | 1.89 MB | Adobe PDF | View/Open | |
10_chapter 6.pdf | 1.07 MB | Adobe PDF | View/Open | |
11_chapter 7.pdf | 1.29 MB | Adobe PDF | View/Open | |
12_chapter 8.pdf | 618.3 kB | Adobe PDF | View/Open | |
13_annexures.pdf | 11.29 MB | Adobe PDF | View/Open | |
80_recommendation.pdf | 700.74 kB | Adobe PDF | View/Open |
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