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http://hdl.handle.net/10603/218613
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DC Field | Value | Language |
---|---|---|
dc.coverage.spatial | Chemistry | |
dc.date.accessioned | 2018-10-16T05:18:56Z | - |
dc.date.available | 2018-10-16T05:18:56Z | - |
dc.identifier.uri | http://hdl.handle.net/10603/218613 | - |
dc.description.abstract | Copper mediated C-heteroatom coupling have been developed as cheaper substitute of expensive Pd/ligand system. Conversely to Pd-mediated cross coupling reactions, mechanism of these reactions are poorly understood and cheaper arylchlorides are extremely poor substrates. Moreover, Deactivation of copper catalyst during course of reaction are not well understood. However, uncertainty about the behavior of copper/ligand system and awaiting activation of cheaper aryl chlorides restricted the wider applications of copper catalyzed reactions. newline newline | |
dc.format.extent | p.167 | |
dc.language | English | |
dc.relation | No. of references 289 | |
dc.rights | university | |
dc.title | Synthetic and Mechanistic Investigations on Copper Mediated CN Bond Formation in Arylation Reactions | |
dc.title.alternative | ||
dc.creator.researcher | Kamlesh Kumar Gurjar | |
dc.subject.keyword | Arylation; Organic Synthesis; Copper-mediated; Density functional calculations; Reaction Mechanism. | |
dc.description.note | Chapter 1 Introduction p.1-5, Chapter 2 A review-Copper mediated cross coupling reactions p.6-20, Chapter 3 Mechanistic studies on Cu-mediated N-arylation reactions p.21-52, Chapter 4 A computational investigation-Deactivation of copper catalyst p.53-61, Chapter 5 Activation of C(aryl)-Cl bond-Synthetic studies p. 62-96, Chapter 6 Activation of C(aryl)-Cl bond-Mechanistic studies p.97-109, Chapter 7 Conclusion and future prospects p.110-113, Appendix-I-IV p.114-166. | |
dc.contributor.guide | Rajendra Kumar Sharma | |
dc.publisher.place | Ahmedabad | |
dc.publisher.university | Gujarat Technological University | |
dc.publisher.institution | Science - Chemistry | |
dc.date.registered | 04-01-2014 | |
dc.date.completed | 06-09-2018 | |
dc.date.awarded | ||
dc.format.dimensions | ||
dc.format.accompanyingmaterial | None | |
dc.source.university | University | |
dc.type.degree | Ph.D. | |
Appears in Departments: | Science - Chemistry |
Files in This Item:
File | Description | Size | Format | |
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01_title page.pdf | Attached File | 77.39 kB | Adobe PDF | View/Open |
02_certificates.pdf | 116.22 kB | Adobe PDF | View/Open | |
03_abstract.pdf | 147.89 kB | Adobe PDF | View/Open | |
04_aknowledgement.pdf | 7.95 kB | Adobe PDF | View/Open | |
05_table of content.pdf | 288.17 kB | Adobe PDF | View/Open | |
06_list of figures.pdf | 309.08 kB | Adobe PDF | View/Open | |
07_chapter1.pdf | 87.87 kB | Adobe PDF | View/Open | |
08_chapter2.pdf | 258.9 kB | Adobe PDF | View/Open | |
09_chapter3.pdf | 2.52 MB | Adobe PDF | View/Open | |
10_chapter4.pdf | 286.69 kB | Adobe PDF | View/Open | |
11_chapter5.pdf | 2.46 MB | Adobe PDF | View/Open | |
12_chapter6.pdf | 694.21 kB | Adobe PDF | View/Open | |
13_chapter7.pdf | 56.96 kB | Adobe PDF | View/Open | |
14_appendices.pdf | 1.15 MB | Adobe PDF | View/Open |
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