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Title: Development of an efficient and Green protocols for C C and C Heteroatom bond formation employing organoboron reagents
Researcher: Toradmal Gopal Kisanrao
Guide(s): Tale R. H.
University: Swami Ramanand Teerth Marathwada University
Completed Date: 29/06/2016
Abstract: Abstract newlineA mild and efficient protocol for the ipso-iodination of aryl boronic acids using N-iodomorpholinium iodide(NIMI) generated in situ from morpholine and molecular iodine as a novel iodinating agent has beendeveloped. The addition of a catalytic amount of copper iodide found to promote rate enhancement ofthe iodination reaction and dramatic increase in the yield depending upon the nature of the boronic acid newlinewas observed. The mechanistic study revealed that depending upon the nature of the substrate, either the classical ipso substitution or copper catalysed iododeborylation pathway overall dominates the present iodination reaction. The features such as mild reaction conditions, operational simplicity, high to excellent yields, excellent functional group compatibility and low catalyst loading make this method potentially useful in organic synthesis. newline
Pagination: n.a.
Appears in Departments:School of Chemical Sciences

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04_declaration.pdf183.71 kBAdobe PDFView/Open
05_acknowledgement pdf.pdf101.33 kBAdobe PDFView/Open
06_contents.pdf383.32 kBAdobe PDFView/Open
07_list_of_tables.pdf82.08 kBAdobe PDFView/Open
08_list_of_figures.pdf6.27 kBAdobe PDFView/Open
09_abbreviations.pdf83.69 kBAdobe PDFView/Open
10_chapter1.pdf1.29 MBAdobe PDFView/Open
11_chapter2.pdf7.94 MBAdobe PDFView/Open
12_chapter3.pdf3.66 MBAdobe PDFView/Open
13_chapter4.pdf2.5 MBAdobe PDFView/Open
14_chapter5.pdf1.53 MBAdobe PDFView/Open
15_conclusion.pdf132.21 kBAdobe PDFView/Open
16_bibliography.pdf561.76 kBAdobe PDFView/Open

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